The following lists only preprints without a corresponding final revised paper.
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04 Apr 2025
StratoBayes: A Bayesian method for automated stratigraphic correlation and age modelling
Kilian Eichenseer, Matthias Sinnesael, Martin R. Smith, and Andrew R. Millard
EGUsphere, https://doi.org/10.5194/egusphere-2025-1355, https://doi.org/10.5194/egusphere-2025-1355, 2025
Preprint under review for GChron (discussion: open, 0 comments)
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StratoBayes is a novel Bayesian method for aligning stratigraphic data from multiple sites. It integrates diverse information, such as geochemical signals and radiometric dates, and provides robust age estimates with quantified uncertainty for all sites. We use StratoBayes to correlate lower Cambrian δ13C records from Morocco with an undated record from Siberia, and estimate the age of the world’s oldest trilobites.
03 Apr 2025
Deglaciation of the Sierra Nevada (USA) during Heinrich Event 1
Richard A. Becker, Aaron M. Barth, Shaun A. Marcott, Basil Tikoff, and Marc W. Caffee
EGUsphere, https://doi.org/10.5194/egusphere-2025-1370, https://doi.org/10.5194/egusphere-2025-1370, 2025
Preprint under review for GChron (discussion: open, 0 comments)
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We report 31 new 10Be and 26 recalculated 36Cl dates from the Sierra Nevada Mountains (USA) and conclude that deglaciation’s final and rapid phase began at 16.4 ± 0.8 ka. In comparing this timing with high-resolution regional paleoclimate proxies, we interpret that rapid deglaciation most likely began at 16.20 ± 0.13 ka, which is indistinguishable in timing from Heinrich Event 1. We interpret that the range’s deglaciation was likely driven by a reunification of the polar jet stream at this time.
20 Mar 2025
Diffusion kinetics of 3He in pyroxene and plagioclase and applications to cosmogenic exposure dating and paleothermometry in mafic rocks
Marie Bergelin, Andrew Gorin, Greg Balco, and William Cassata
EGUsphere, https://doi.org/10.5194/egusphere-2025-928, https://doi.org/10.5194/egusphere-2025-928, 2025
Preprint under review for GChron (discussion: open, 0 comments)
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Helium gas accumulates over time in minerals, but loss can occur depending on temperature. If partially retained, its loss can potentially be used for determining past surface temperatures. This study uses a model that accounts for complex gas loss to analyze helium retention in two minerals commonly found on the surface of Antarctica. We find one of the minerals retains helium while the other loses nearly all of the gas within hundred years, making it unsuitable as a climate reconstruction.
18 Mar 2025
Interlaboratory reproducibility of ID-TIMS U–Pb geochronology evaluated with a pre-spiked natural zircon solution
Dawid Szymanowski, Jörn-Frederik Wotzlaw, Maria Ovtcharova, Blair Schoene, Urs Schaltegger, Mark D. Schmitz, Ryan B. Ickert, Cyril Chelle-Michou, Kevin R. Chamberlain, James L. Crowley, Joshua H. F. L. Davies, Michael P. Eddy, Sean P. Gaynor, Alexandra Käßner, Michael T. Mohr, André N. Paul, Jahan Ramezani, Simon Tapster, Marion Tichomirowa, Albrecht von Quadt, and Corey J. Wall
EGUsphere, https://doi.org/10.5194/egusphere-2025-1001, https://doi.org/10.5194/egusphere-2025-1001, 2025
Preprint under review for GChron (discussion: open, 1 comment)
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We present the first community evaluation of the reproducibility of U–Pb zircon geochronology by ID-TIMS. Eleven labs in the experiment analysed aliquots of the same, homogenised, pre-spiked solution of natural zircon. This removed geological bias inherent to using natural zircon grain populations and allowed focussing the study on final lab preparation and mass spectrometry. We discuss remaining sources of inter-lab bias and propose areas of improvement of analytical methods.
12 Mar 2025
The conflict between sampling resolution and stratigraphic constraints from a Bayesian perspective: OSL and radiocarbon case studies
Guillaume Guérin, Pierre Guitton-Boussion, Imène Bouafia, and Anne Philippe
EGUsphere, https://doi.org/10.5194/egusphere-2025-890, https://doi.org/10.5194/egusphere-2025-890, 2025
Preprint under review for GChron (discussion: open, 0 comments)
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Bayesian modelling is often used to refine numerically dated chronological sequences, e.g., by making use of stratigraphic constraints. First, a high-resolution dataset based on luminescence dating is modelled with the dedicated R package BayLum. Then, three Bayesian modelling tools – namely BayLum, Chronomodel and OxCal – are compared using a high-resolution, radiocarbon dataset. Modelling artefacts are identified; the strengths and weaknesses of the models are discussed.
07 Mar 2025
Technical Note: Incorporating topographic deflection effects into thermal history modelling
Richard A. Ketcham
EGUsphere, https://doi.org/10.5194/egusphere-2025-901, https://doi.org/10.5194/egusphere-2025-901, 2025
Preprint under review for GChron (discussion: open, 0 comments)
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This technical note develops and demonstrates an improvement in how to calculate the temperatures experienced by rocks as they come to the Earth surface due to erosion in mountainous regions. The solution is fast and flexible, and works even in areas where erosion rates have varied through time. The new method has been added to software used to interpret geochronologic data to help discern the history of mountain ranges.
06 Mar 2025
How much K is oK? – Evaluating different methods for K-concentration determination and the effect of the internal K-concentration on feldspar luminescence dating
Linda Andrea Elisabeth Maßon, Svenja Riedesel, Stephan Opitz, Anja Zander, Anthony Bell, Hanna Cieszynski, and Tony Reimann
EGUsphere, https://doi.org/10.5194/egusphere-2025-806, https://doi.org/10.5194/egusphere-2025-806, 2025
Preprint under review for GChron (discussion: open, 1 comment)
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We evaluate different methods for the potassium (K) concentration determination in feldspars and the impact of the K-concentrations on dose rate calculations for feldspar luminescence dating. Our results show discrepancies between published and our measured K-concentrations. Therefore, we emphasise to measure K-concentrations via bulk measurements and single-grain techniques to obtain more accurate results.
27 Feb 2025
Accuracy and validity of maximum depositional ages in light of tandem (laser ablation + isotope dilution) U–Pb detrital zircon geochronology, including n = 1 results from northern Alaska
Trystan M. Herriott, James L. Crowley, Marwan A. Wartes, David L. LePain, and Mark D. Schmitz
EGUsphere, https://doi.org/10.5194/egusphere-2025-727, https://doi.org/10.5194/egusphere-2025-727, 2025
Preprint under review for GChron (discussion: open, 0 comments)
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Paired low- and high-precision U–Pb geochronology data are evaluated to better understand young bias in laser ablation dates and detrital zircon maximum depositional ages (MDAs). We redefine the reference for MDA accuracy as the true age of the youngest analyzed population and reframe MDA algorithm assessments around validity. This study highlights opportunities to refine MDA research and anticipates continued community efforts to further improve accuracy of laser ablation zircon geochronology.
19 Feb 2025
Exploring the relationships between Electron Spin Resonance (ESR)/Optically Stimulated Luminescence (OSL) properties and trace element composition in various quartz-bearing bedrocks (Strengbach catchment, Vosges)
Hélène Tissoux, Magali Rizza, Claire Aupart, Gilles Rixhon, Pierre G. Valla, Manon Boulay, Philippe Lach, and Pierre Voinchet
EGUsphere, https://doi.org/10.5194/egusphere-2025-182, https://doi.org/10.5194/egusphere-2025-182, 2025
Preprint under review for GChron (discussion: open, 0 comments)
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This study, using ESR, OSL, and LA-ICPMS trace element analyses, reveals significant relationships between quartz OSL/ESR sensitivities and bedrock characteristics. Trace element compositions appear to influence the OSL and ESR-Ti sensitivities, the last being weak in quartz extracted from metamorphic or deformed rocks. Pressure may take a part in OSL/ESR-Ti sensitivities variability while ESR Al intensities could be linked to initial fluid composition and crystallization conditions
13 Feb 2025
Broken 206Pb/238U carbonate chronometers and 207Pb/235U fixes
Pieter Vermeesch, Noah McLean, Anton Vaks, Tzahi Golan, Sebastian F. M. Breitenbach, and Randall Parris
EGUsphere, https://doi.org/10.5194/egusphere-2025-432, https://doi.org/10.5194/egusphere-2025-432, 2025
Preprint under review for GChron (discussion: open, 1 comment)
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U-Pb dating of cave sediments has provided important new time constraints on the evolution of cave-dwelling organisms (including early humans), and of Earth's climate during the past 5 million years. This paper shows that the most common type of U-Pb dating, which uses 238U and 206Pb, can be inaccurate beyond 2 million years ago. It proposes an alternative type of U-Pb dating, using 235U and 207Pb, as a more accurate alternative.
07 Feb 2025
Zircon micro-inclusions as an obstacle for in situ garnet U-Pb geochronology: An example from the As Sifah eclogite locality, Oman
Jesse B. Walters, Joshu M. Garber, Aratz Beranoaguirre, Leo Millonig, Axel Gerdes, Tobias Grützner, and Horst R. Marschall
EGUsphere, https://doi.org/10.5194/egusphere-2025-366, https://doi.org/10.5194/egusphere-2025-366, 2025
Revised manuscript under review for GChron (discussion: final response, 4 comments)
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Garnet U-Pb dating is useful for dating geologic events. However, contamination by U-rich minerals included in garnet is a risk. Inclusions are often spotted by high-U spikes or large errors in the age. We dated garnets in metamorphic rocks and calculated ages 10–15 Myr older than expected, reflecting contamination by the mineral zircon. We provide recommendations for identifying contamination and suggest that the bulk dating of zircon inclusions in garnet may also provide valuable information.
29 Jan 2025
Technical note: 21Ne in the CoQtz-N quartz standard material
Greg Balco
EGUsphere, https://doi.org/10.5194/egusphere-2025-149, https://doi.org/10.5194/egusphere-2025-149, 2025
Preprint under review for GChron (discussion: final response, 4 comments)
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This paper describes measurements of cosmogenic neon-21 concentrations in a widely distributed mineral standard material that is routinely used for quality control and interlaboratory comparison for measurements of other cosmic-ray-produced nuclides useful for various geochronology applications. Broadly, this facilitates improvement of precision and accuracy of these measurements and their applications in geochronology.
28 Jan 2025
Rapid dose rate estimation for trapped charge dating using pXRF measurements of potassium concentration
Sam Woor, Mitch K. D'Arcy, Olav B. Lian, Maria Schaarschmidt, and Julie A. Durcan
EGUsphere, https://doi.org/10.5194/egusphere-2025-55, https://doi.org/10.5194/egusphere-2025-55, 2025
Preprint under review for GChron (discussion: final response, 3 comments)
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We show that portable X-ray fluorescence can be used to rapidly (c. 90 s) estimate the rate of background radioactivity in sediment used to calculate burial ages in trapped charge dating studies. This procedure involves inputting a measurement of potassium concentration into a set of simple linear equations, defined by a large, training dataset. Results show good agreement with high-precision methods. Our rapid method will help to quickly generate burial age estimates.
15 Jan 2025
Further investigations into the accuracy of infrared-radiofluorescence (IR-RF) and its inter-comparison with infrared photoluminescence (IRPL) dating
Mariana Sontag-González, Madhav K. Murari, Mayank Jain, Marine Frouin, and Markus Fuchs
Geochronology Discuss., https://doi.org/10.5194/gchron-2024-36, https://doi.org/10.5194/gchron-2024-36, 2025
Revised manuscript under review for GChron (discussion: final response, 4 comments)
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We tested the reliability of infrared-radiofluorescence (IR-RF) dating of K-feldspar on samples of known age. We compare several measurement protocols and analysis variants and determine the most appropriate version. Additionally, we compare these results with those obtained using infrared photoluminescence (IRPL), an alternative dating method for K-feldspar, for the same samples. Our results confirm the dating potential of IR-RF and highlight similarities and differences to other methods.
09 Jan 2025
40Ar/39Ar age constraints on the formation of fluid-rich quartz veins from the NW Rhenohercynian zone (Rursee area, Germany)
Akbar Aydin Oglu Huseynov, Jan R. Wijbrans, Klaudia F. Kuiper, and Jeroen van der Lubbe
Geochronology Discuss., https://doi.org/10.5194/gchron-2024-35, https://doi.org/10.5194/gchron-2024-35, 2025
Revised manuscript accepted for GChron (discussion: closed, 9 comments)
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This study focuses on quartz veins in Germany's Rursee area, formed during the Variscan orogeny and reactivated by tectonic forces in the Jurassic-Cretaceous period. Using advanced isotopic dating, researchers revealed precise ages, showing how these veins shaped fluid flow and quartz recrystallization. The work addresses the challenge of dating fluid activity and provides new insights into Earth's geological history, offering a method that can be applied to similar studies in other regions.
09 Dec 2024
Paired 14C-10Be exposure ages from Mount Murphy, West Antarctica: Implications for accurate and precise deglacial chronologies
Jonathan R. Adams, Dylan H. Rood, Klaus Wilcken, Stephen J. Roberts, and Joanne S. Johnson
Geochronology Discuss., https://doi.org/10.5194/gchron-2024-34, https://doi.org/10.5194/gchron-2024-34, 2024
Manuscript not accepted for further review (discussion: closed, 6 comments)
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Ice sheet mass loss is adding to sea-level rise, and is expected to increase, but by how much and how fast remains uncertain. Isotopes produced in rock at the Earth’s surface provide records of past ice sheet thinning which help predict future change but are more effective if they are precise enough to determine past changes to the nearest thousand years. The precision of carbon-14, an isotope which is guaranteed to record past change since the last ice age, can be improved.
06 Dec 2024
Technical Note: Improved volume and derived value calculations for polished zircon
Barra A. Peak
Geochronology Discuss., https://doi.org/10.5194/gchron-2024-33, https://doi.org/10.5194/gchron-2024-33, 2024
Preprint under review for GChron (discussion: final response, 4 comments)
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Conventional (U-Th)/He thermochronology requires accurate calculation of mineral grain volumes, often based on approximations to an ideal geometry. However, there are many instances where knowingly altering the geometry through polishing mineral grains for additional in situ data collection is desirable. This contribution provides a new method to calculate polished grain volume and other derived data for zircon (U-Th)/He thermochronology using no-added-cost modifications of existing workflows.
22 Nov 2024
Double dating in the Middle Pleistocene: assessing the consistency and performance of the carbonate U–Th and U–Pb dating methods
Timothy J. Pollard, Jon D. Woodhead, Russell N. Drysdale, R. Lawrence Edwards, Xianglei Li, Ashlea N. Wainwright, Mathieu Pythoud, Hai Cheng, John C. Hellstrom, Ilaria Isola, Eleonora Regattieri, Giovanni Zanchetta, and Dylan S. Parmenter
EGUsphere, https://doi.org/10.5194/egusphere-2024-3594, https://doi.org/10.5194/egusphere-2024-3594, 2024
Preprint under review for GChron (discussion: final response, 4 comments)
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The uranium-thorium and uranium-lead radiometric dating methods are both capable of dating carbonate samples ranging in age from about 400,000 to 650,000 years. Here we test agreement between the two methods by 'double dating' speleothems (i.e. secondary cave mineral deposits) that grew within this age range. We demonstrate excellent agreement between the two dating methods and discuss their relative strengths and weaknesses.
19 Nov 2024
Environmental Gamma Dose Rate Measurements using CZT Detectors
Sebastian Kreutzer, Loïc Martin, Didier Miallier, and Norbert Mercier
Geochronology Discuss., https://doi.org/10.5194/gchron-2024-31, https://doi.org/10.5194/gchron-2024-31, 2024
Revised manuscript accepted for GChron (discussion: closed, 4 comments)
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Accurate readings on the environmental gamma dose rate are important. Portable gamma-ray detectors, such as NaI or LaBr3-based, are easy to handle and affordable. Limited information on alternatives, like CZT (Cadmium Zinc Telluride) detectors is available. We tested CZT detectors and found them suitable for in-field deployment. We used simulations and field tests to evaluate the optimal energy threshold for direct dose rate readings, making the CZT system a reliable alternative.
14 Nov 2024
A comparison between in situ monazite Lu–Hf and U–Pb geochronology
Alexander T. De Vries Van Leeuwen, Stijn Glorie, Martin Hand, Jacob Mulder, and Sarah E. Gilbert
Geochronology Discuss., https://doi.org/10.5194/gchron-2024-29, https://doi.org/10.5194/gchron-2024-29, 2024
Revised manuscript accepted for GChron (discussion: closed, 4 comments)
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In this contribution we demonstrate in situ monazite Lu–Hf dating and compare results with U–Th–Pb dating. We present data from monazite reference materials and complex samples to demonstrate the viability of this method. We show that in situ Lu–Hf dating of monazite can resolve multiple age populations and may find use where the U–Th–Pb system is compromised by Pb-loss, non-radiogenic Pb contamination, excess 206 Pb, low U contents, or a combination of these factors.
28 Oct 2024
Discordance Dating: A New Approach for Dating Sedimentary Alteration Events
Jesse R. Reimink, Renan Beckman, Erik Schoonover, Max Lloyd, Joshua Garber, Joshua H. F. L. Davies, Alexander Cerminaro, Morgann G. Perrot, and Andrew J. Smye
Geochronology Discuss., https://doi.org/10.5194/gchron-2024-27, https://doi.org/10.5194/gchron-2024-27, 2024
Preprint under review for GChron (discussion: final response, 7 comments)
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This manuscript presents a new method to date geological events affecting sedimentary rocks. This method relies on the potential for the zircon U-Pb system to be disturbed during fluid-flow, alteration, and metamorphic events in sedimentary rocks. This manuscript presents synthetic datasets for testing the accuracy and precision of the discordance dating method, as well as data from detrital zircons found in the contact metamorphic aureole surround the Alta Stock.
10 Oct 2024
The quantification of downhole fractionation for laser ablation mass spectrometry
Jarred Cain Lloyd, Carl Spandler, Sarah E. Gilbert, and Derrick Hasterok
EGUsphere, https://doi.org/10.5194/egusphere-2024-2908, https://doi.org/10.5194/egusphere-2024-2908, 2024
Preprint under review for GChron (discussion: final response, 4 comments)
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Laser-based dating of rocks and minerals is invaluable in geoscience. This study presents a significant advancement in our ability to model and correct for a process called downhole fractionation (DHF) that can impact the accuracy and uncertainty of dates. We develop an algorithm that quantitatively models DHF patterns. The implications are far-reaching: improved accuracy, reduced uncertainty, and easier comparisons between different samples and laboratories.
08 Oct 2024
Terrestrial Cosmogenic Nuclide depth profiles used to infer changes in Holocene glacier cover, Vintage Peak, Southern Coast Mountains, British Columbia
Adam C. Hawkins, Brent M. Goehring, and Brian Menounos
EGUsphere, https://doi.org/10.5194/egusphere-2024-2900, https://doi.org/10.5194/egusphere-2024-2900, 2024
Revised manuscript accepted for GChron (discussion: final response, 4 comments)
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We use a method called cosmogenic nuclide dating on bedrock surfaces and moraine boulders to determine the relative length of time an alpine glacier was larger or smaller than its current extent over the past 15 thousand years. We also discuss several important limitations to this method. This method gives information on the duration of past ice advances and is useful in areas without other materials that can be dated.
07 Oct 2024
Technical Note: Benchmark time-temperature paths provide a shared framework for evaluating and communicating thermochronologic data interpretation
Andrea L. Stevens Goddard, Kendra E. Murray, Alyssa L. Abbey, and Mark Wildman
Geochronology Discuss., https://doi.org/10.5194/gchron-2024-20, https://doi.org/10.5194/gchron-2024-20, 2024
Manuscript not accepted for further review (discussion: closed, 5 comments)
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We present a set of six standardized time-temperature histories, which we call benchmark paths, that can be used by the low-temperature thermochronology community to evaluate and visualize the sensitivity of thermochronologic systems to the variables inherent in the interpretation of thermochronologic data. As an example, we present a method for “tuning” each benchmark path to eleven published kinetics models (for the apatite (U-Th-Sm)/He, apatite fission-track, and zircon (U-Th)/He systems).
30 Sep 2024
Nonparametric estimation of age-depth models from sedimentological and stratigraphic information
Niklas Hohmann, David De Vleeschouwer, Sietske Batenburg, and Emilia Jarochowska
EGUsphere, https://doi.org/10.5194/egusphere-2024-2857, https://doi.org/10.5194/egusphere-2024-2857, 2024
Preprint under review for GChron (discussion: final response, 12 comments)
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Age-depth models assign ages to sampling locations (e.g., in drill cores), making them crucial to determined timing and pace of past changes. We present two methods to estimate age-depth models from sedimentological and stratigraphic information, resulting in richer and more empirically realistic age-depth models. As a use case, we determine (1) the timing of the Frasnian-Famennian extinction and (2) examine the duration of PETM, an potential deep time analogue for anthropogenic climate change.
29 Aug 2024
The virtual spot approach: a simple method for image U-Pb carbonate geochronology by high-repetition rate LA-ICP-MS
Guilhem Hoareau, Fanny Claverie, Christophe Pecheyran, Gaëlle Barbotin, Michael Perk, Nicolas E. Beaudoin, Brice Lacroix, and E. Troy Rasbury
EGUsphere, https://doi.org/10.5194/egusphere-2024-2366, https://doi.org/10.5194/egusphere-2024-2366, 2024
Preprint under review for GChron (discussion: final response, 3 comments)
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We present an approach to U-Pb dating of carbonates using isotopic image maps. The maps are divided into squares called virtual spots. For each virtual spot, statistical values (mean, uncertainty) are used to determine the age. The user can modify the size and location of the virtual spots and select those that give the most robust age. This approach, applied to high spatial resolution images, makes it possible for the first time to obtain satisfactory ages on images as small as 100 µm x 100 µm.
28 Aug 2024
Global analysis of in situ cosmogenic 26Al/10Be ratios in fluvial sediments indicates widespread sediment storage and burial during transport
Christopher Halsted, Paul Bierman, Alexandru Codilean, Lee Corbett, and Marc Caffee
Geochronology Discuss., https://doi.org/10.5194/gchron-2024-22, https://doi.org/10.5194/gchron-2024-22, 2024
Revised manuscript under review for GChron (discussion: final response, 4 comments)
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Sediment generation on hillslopes and transport through river networks are complex processes that influence landscape evolution. In this study compiled sand from over 600 river basins and measured its (very subtle) radioactivity to unravel timelines of sediment routing around the world. With this data we empirically confirm that sediment from large lowland basins in tectonically stable regions typically experiences long periods of burial, while sediment moves rapidly through small upland basins.
08 Aug 2024
Short Communication: A database of the global distribution of (U-Th)/He ages and U, Th contents of goethites
Hevelyn S. Monteiro, Kenneth A. Farley, and Paulo M. Vasconcelos
Geochronology Discuss., https://doi.org/10.5194/gchron-2024-13, https://doi.org/10.5194/gchron-2024-13, 2024
Revised manuscript under review for GChron (discussion: final response, 4 comments)
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We have built a database of (U-Th)/He ages and U and Th contents of goethites from various weathering environments. The database contains 2597 (U-Th)/He ages of goethites from 10 countries. The findings presented in this manuscript contribute insights onto the distribution of dated goethites from different environments globally and into the Earth's Cenozoic weathering history.
24 Jul 2024
Cosmogenic 3He dating of olivine with tightly retained mantle 3He, Volcano Mountain, Yukon
Jessica Mueller, Jeffrey Bond, Kenneth Farley, and Brent Ward
Geochronology Discuss., https://doi.org/10.5194/gchron-2024-15, https://doi.org/10.5194/gchron-2024-15, 2024
Revised manuscript accepted for GChron (discussion: final response, 6 comments)
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We obtained a cosmogenic 3He (3Hec) exposure age of 10.9 ka ± 1.1 ka for the youngest lava flow at Volcano Mountain (VM) in Yukon, Canada. Initially, olivine grains from the flow were crushed to release mantle He from fluid inclusions and subsequently fused to release 3Hec from the matrix. However, mantle He was significantly retained in fusions. We circumvented this problem by step-heating powdered olivine at three temperature steps, where the lowest temperature step successfully isolated 3Hec.
16 Feb 2024
A method for quantifying the time of cooling in thermochronometric inversions
Kalin T. McDannell and C. Brenhin Keller
Geochronology Discuss., https://doi.org/10.5194/gchron-2024-3, https://doi.org/10.5194/gchron-2024-3, 2024
Revised manuscript has not been submitted (discussion: closed, 6 comments)
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We introduce a new statistical method for determining the time of "peak cooling" in thermochronological inversions. Specifically, we focus on the time-temperature paths that intersect the half-maximum cooling isotherm, signifying the zenith or most rapid cooling within a defined interval. The resultant interpolated time distribution provides a systematic metric, particularly applicable for evaluating model cooling characterized by relatively smooth histories featuring a single inflection point.
14 Feb 2024
Technical note: a new analytical protocol for apatite (U-Th)/He and trace element analysis (incorporating a continuous ramped heating measurement system for the He)
Alexis Derycke, Nathan Cogné, Dominique Bavay, David Vilbert, Lionel Dutruch, Sebastien Ternois, Gilles Ruffet, Marc Jolivet, and Kerry Gallagher
Geochronology Discuss., https://doi.org/10.5194/gchron-2024-6, https://doi.org/10.5194/gchron-2024-6, 2024
Publication in GChron not foreseen (discussion: closed, 10 comments)
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This note details a development of the (U-Th)/He method for dating apatite crystals in low-temperature thermochronology. Our innovation simplifies analysis protocols for gases (He) and crystals (U, Th, etc.), aiming to expedite data production and enhance study reliability.
28 Jun 2023
Constraints on average alpha recoil distance during 238U decay in baddeleyite (ZrO2) from atom probe tomography
Donald Wayne Davis, Steven Denyszyn, and Denis Fougerouse
Geochronology Discuss., https://doi.org/10.5194/gchron-2023-15, https://doi.org/10.5194/gchron-2023-15, 2023
Preprint withdrawn (discussion: closed, 6 comments)
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Decay of U to Pb in the mineral baddeleyite is used for precisely dating mafic rocks, but some daughter Pb atoms can be ejected out of the crystal, resulting in an age that appears too young. Atom Probe Tomography was used to map the distribution of U and Pb atoms in 3 dimensions within a baddeleyite crystal and estimate the average distance that Pb atoms are displaced by decay of U. This allows us to correct the measured age on a baddeleyite crystal knowing its size and shape.
16 Jun 2023
On etching, selection and measurement of confined fission tracks in apatite
Raymond Charles Jonckheere
Geochronology Discuss., https://doi.org/10.5194/gchron-2023-13, https://doi.org/10.5194/gchron-2023-13, 2023
Manuscript not accepted for further review (discussion: closed, 8 comments)
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We investigate the relationship between damage trails from uranium fission in apatite and the etched tracks measured with an optical microscope. We aim to understand sampling biases and to improve etching, selection and measurement protocols. The track orientation and length, apatite and track etch rate, and effective etch time co-determine whether a track is suitable for measurement. Reliable data are attainable because the specific sample properties have but a limited effect on these factors.
02 May 2023
Technical Note: Pb-loss-aware Eruption/Deposition Age Estimation
C. Brenhin Keller
Geochronology Discuss., https://doi.org/10.5194/gchron-2023-9, https://doi.org/10.5194/gchron-2023-9, 2023
Publication in GChron not foreseen (discussion: closed, 6 comments)
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As a result of increasing precision and accuracy in geochronology, interpreting complicated age spectra has become increasingly important, since individual mineral ages often do not directly date the actual geologic process of interest. Here we propose a method for estimating the age of eruption or deposition of a set of minerals dated by the U-Pb system which, in contrast to previous approaches, remains accurate even when the dated minerals have experienced loss of the daughter product Pb.
14 Nov 2022
Multiple Early Holocene eruptions of Katla produced tephra layers with similar composition to the Vedde Ash
David Harning, Thor Thordarson, Áslaug Geirsdóttir, Gifford Miller, and Christopher Florian
Geochronology Discuss., https://doi.org/10.5194/gchron-2022-26, https://doi.org/10.5194/gchron-2022-26, 2022
Preprint withdrawn (discussion: closed, 8 comments)
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Volcanic ash layers are a common tool to synchronize records of past climate, and their estimated age relies on external dating methods. Here, we show that the chemical composition of the well-known, 12000 year-old Vedde Ash is indistinguishable with several other ash layers in Iceland that are ~1000 years younger. Therefore, chemical composition alone cannot be used to identify the Vedde Ash in sedimentary records.
11 Oct 2022
Origin of Great Unconformity Obscured by Thermochronometric Uncertainty
Matthew Fox, Adam G. G. Smith, Pieter Vermeesch, Kerry Gallagher, and Andrew Carter
Geochronology Discuss., https://doi.org/10.5194/gchron-2022-23, https://doi.org/10.5194/gchron-2022-23, 2022
Publication in GChron not foreseen (discussion: closed, 6 comments)
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The Great Unconformity represents an enormous amount of time lost from the sedimentary record. Its origin is debated, in part, due to different approaches used to interpret zircon (U–Th)/He ages. This thermochronometric system is ideal for this problem because the temperature sensitivity varies according to radiation damage. Here we explore the uncertainty associated with the radiation damage model and show how this limits our ability to resolve the origin of the Great Unconformity.
05 Apr 2022
Supergene phases from ferruginous duricrusts: non-destructive microsampling and mineralogy prior to (U-Th)/He geochronological analysis
Karina Patricia Prazeres Marques, Thierry Allard, Cécile Gautheron, Benoît Baptiste, Rosella Pinna-Jamme, Guillaume Morin, Ludovic Delbes, and Pablo Vidal-Torrado
Geochronology Discuss., https://doi.org/10.5194/gchron-2022-9, https://doi.org/10.5194/gchron-2022-9, 2022
Preprint withdrawn (discussion: closed, 0 comments)
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We proposed a new non-destructive mineralogical methodology on inframilimetric grains that allows to quantify the hematite and goethite content and hematite/goethite ratio of grains prior to (U-Th)/He geochronological analysis. (U-Th)/He data performed on different aliquots with different acquisition time shows no remarkable differences in age, opening a new way to investigate the (U-Th)/He data evolution in supergene lateritic duricrusts.
16 Jun 2021
Paleomagnetic secular variation for a 21,000-year sediment sequence from Cascade Lake, north-central Brooks Range, Arctic Alaska
Douglas P. Steen, Joseph S. Stoner, Jason P. Briner, and Darrell S. Kaufman
Geochronology Discuss., https://doi.org/10.5194/gchron-2021-19, https://doi.org/10.5194/gchron-2021-19, 2021
Publication in GChron not foreseen (discussion: closed, 4 comments)
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Paleomagnetic data from Cascade Lake (Brooks Range, Alaska) extend the radiometric-based age model of the sedimentary sequence extending back 21 kyr. Correlated ages based on prominent features in paleomagnetic secular variations (PSV) diverge from the radiometric ages in the upper 1.6 m, by up to about 2000 years at around 4 ka. Four late Holocene cryptotephra in this section support the PSV chronology and suggest the influence of hard water or aged organic material.
17 May 2021
Evidence for old carbon contamination in 14C wiggle-match age series for the 946 CE eruption of Changbaishan volcano
Richard N. Holdaway, Ben Kennedy, Brendan M Duffy, Jiandong Xu, and Clive Oppenheimer
Geochronology Discuss., https://doi.org/10.5194/gchron-2021-13, https://doi.org/10.5194/gchron-2021-13, 2021
Revised manuscript not accepted (discussion: closed, 4 comments)
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Prehistoric volcanic eruptions are often dated by wiggle matching series of radiocarbon ages on tree rings to standard calibration curves, ignoring potential contamination by 'old' carbon given off by the volcano. We modeled the effects of low amounts of contamination on wiggle match dates for the 10th century Changbaishan eruption and found evidence of contamination in all. We propose a new protocol to identify the presence of contamination, and provide more secure dates for major eruptions.
21 Dec 2020
Direct dating of overprinting fluid systems in the Martabe
epithermal gold deposit using highly retentive alunite
Jack Muston, Marnie Forster, Conrad Alderton, Shawn Crispin, and Gordon Lister
Geochronology Discuss., https://doi.org/10.5194/gchron-2020-41, https://doi.org/10.5194/gchron-2020-41, 2020
Publication in GChron not foreseen (discussion: closed, 2 comments)
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The timing and duration of fluid activity within a gold deposit enables a greater understanding of how the deposit evolved and thus help future mineral exploration. This research uses high resolution dating methods to unravel the overprinting fluid activity at the Martabe gold field in Sumatra. Methods outline in this report can be applied to deposits globally.
19 Jun 2020
Potassium isotopic variability and implications for 40K-based
geochronology
Leah E. Morgan
Geochronology Discuss., https://doi.org/10.5194/gchron-2020-18, https://doi.org/10.5194/gchron-2020-18, 2020
Publication in GChron not foreseen (discussion: closed, 4 comments)
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Potassium-based geochronology, including the 40Ar/39Ar and K-Ar methods, provides critical constraints on the timing and duration of many events and processes in earth history. These methods assume that a key parameter, the fraction of potassium with a mass of 40, does not vary in some relevant materials. Some recent work has identified some variability in these materials. This work examines the effects of this variability on calculated K-Ar and 40Ar/39Ar ages.
10 Feb 2020
A closer look at IRSL SAR fading data and their implication for luminescence dating
Annette Kadereit, Sebastian Kreutzer, Christoph Schmidt, and Regina DeWitt
Geochronology Discuss., https://doi.org/10.5194/gchron-2020-3, https://doi.org/10.5194/gchron-2020-3, 2020
Preprint withdrawn (discussion: closed, 5 comments)